Photox Optical Systems
LBO crystal LBO crystal LBO crystal LBO crystal LBO crystal LBO crystal LBO crystal LBO crystal

LBO Crystal- Lithium Triborate

(LiB3O5)

LBO's high damage threshold,wide acceptance angle, good thermal stability and wide transmission range make it ideal for frequency doubling of high power lasers. The shortest phase matchable wavelength fo direct SHG is 554 nm. It promises to become the preferred crystal for frequency doubling or tripling of high power Nd:YAG and Nd:YLF lasers. It is also frequently used for SHG of Ti:Sapphire, Alexandrite, Cr:LiSAF lasers and diode pumped Nd doped lasers. Other well known applications using LBO include OPO and OPA pumped by Eximer lasers and the harmonics of Nd:YAG lasers.

Advantages of LBO

Broad transparency range from 160nm to 2600nm (SHG range from 0.55µm to 2.6µm).

High optical homogeneity (Dn»10-6/cm) and inclusion free.

Relatively large effective SHG coefficient - about 3x that of KDP.

Wide acceptance angle and small walk-off.

No walk-off and maximum effective coefficient using non-critical phase-matching.

High damage threshold - 18.9GW/cm2 for a 1.3ns laser at 1.054µm.

 

Physical properties

Crystal structure/point group orthorhombic/mm2
Lattice parameters a=0.8447nm, b=0.7379nm, c=0.5140nm, Z=2
Melting point 834ºC (decomposition)
Density 2.47 g.cm-3
Mohs hardness ~6
Absorption coefficient <0.1%/cm @ 1.64 µm
Thermal expansion coefficient ax= 10.8´10-5/K
ay= -8.8´10-5/K
az= 3.4´10-5/K

 

Optical properties

Transmission range 160 - 3200 nm
Nonlinear optical coefficient 3 x 10-9 e.s.u.(effective SHG coefficient ~3 x KDP)
Acceptance angle 25 mrad (95 mrad at q=90o)
Damage threshold 25 GW cm-2 (1064 nm, 0.1 ns)
Dimensions As large as 20 x 20 x 20 mm and thickness <0.1 mm are available
Refractive indices
@1064nm @532nm
nx[100] 1.5656 1.5785
ny[010] 1.5905 1.6065
nz[001] 1.6055 1.6212
Sellmeier equations:(in µm) nx2= 2.45316 + 0.01150/(l2-0.01058)- 0.01123l2
ny2= 2.53969 + 0.01249/(l2-0.01339)- 0.02029l2
nz2= 2.58515 + 0.01412/(l2-0.00467)- 0.01850l2

LBO is a negative biaxial crystal with the principle axes x, y and z (nz>ny>nx) parallel to the crystallographic axes a, c and b respectively.

 

Finished Quality Indications

End faces flatness (transmitting <l/8 @633nm
wavefront distortion also)
Scratch/Dig 10/5 to MIL-0-13830A
Clear aperture >90% of central area. No visible scattering
paths or centres are seen using a 30mW
He-Ne laser.
Dimension tolerance W±0.1mm x H±0.1mm x L+0.2/-0.1mm
Parallelism better than 20 arc seconds
Perpendicularity arc minutes
Angular tolerance Dq< ±0.5o, Df< ±0.5o
Damage threshold 15 GW/cm2 for a single mode 1.3ns
1 Hz laser at 1.064µm
1 GW/cm2 for a cw, mode-locked laser at
1.064µm

The crystals are guaranteed to the above specification.

Coating and Mounts

The LBO may be provided with AR-coatings or cut with Brewster's angle faces for intra-cavity use. Mounts are also available.

Handling Advice & Technical Support

Users are advised to store and use LBO in dry conditions as LBO is slightly hygroscopic. Care must be taken to protect the polished surface of LBO from scratching and dust. If necessary cleaning can be achieved with soft silk dampened with pure organic solvents such as 50:50 alcohol and ether.